Direct air-induced arylphosphinoyl radicals for the synthesis of benzo[<i>b</i>]phosphole oxides
Mingqing Huang, Haiyang Huang, Mengyao You, Xinxin Zhang, Longgen Sun, Chao Chen, Zhichao Mei, Ruchun Yang, Qiang Xiao
Abstract
The direct air-oxidation strategy enables the transformation of arylphosphine oxides into phosphinoyl radicals, which are subsequently used in the synthesis of benzo[ b ]phosphole oxides by combining with various alkynes.
Topics & Concepts
PhospholeRadicalChemistryOxidePhotochemistryOrganic chemistryRadical Photochemical ReactionsOrganophosphorus compounds synthesisSulfur-Based Synthesis Techniques