Single-crystal-to-single-crystal transformation and proton conductivity of three hydrogen-bonded organic frameworks
Yijie Wang, Minghui Zhang, Qianqian Yang, Jianbo Yin, Di Liu, Yanxue Shang, Zixi Kang, Rongming Wang, Daofeng Sun, Jianzhuang Jiang
Abstract
groups in UPC-H7 and UPC-H8 facilitate the diffusion of water molecules into their anhydrous structures to form hydrous UPC-H9. Their proton conductivity was studied under different humidity at varying temperature, showing that the proton conductivity is closely related to water molecules entering the crystal structures arising from the hydrogen bonded reorganization in combination with the triaxial single-crystal proton conductivity tests.
Topics & Concepts
ProtonConductivityTransformation (genetics)Materials scienceMoleculeHydrogen bondCrystal (programming language)HydrogenSingle crystalAdaptabilityCrystallographyChemical engineeringChemical physicsChemistryPhysical chemistryOrganic chemistryComputer sciencePhysicsGeneBiochemistryQuantum mechanicsBiologyEcologyProgramming languageEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsFuel Cells and Related Materials