Impact of Defects and Crystal Size on Negative Gas Adsorption in DUT-49 Analyzed by <i>In Situ</i> <sup>129</sup> Xe NMR Spectroscopy
Simon Krause, Florian Reuter, Sebastian Ehrling, Volodymyr Bon, Irena Senkovska, Stefan Kaskel, Eike Brunner
Abstract
Xe NMR. In comparison to the results obtained for crystals with different size, we find pronounced changes of the adsorption behavior and influence of the chemical shift only for very high concentrations of defects, which further emphasizes the important role of particle size phenomena.
Topics & Concepts
AdsorptionCrystal (programming language)In situMaterials scienceSpectroscopyChemical physicsAnalytical Chemistry (journal)CrystallographyChemistryPhysical chemistryOrganic chemistryPhysicsComputer scienceQuantum mechanicsProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced NMR Techniques and ApplicationsPhase Equilibria and Thermodynamics