A stable lanthanum hydroxamate metal–organic framework with radical character and electrical conductivity
Yong Yan, Ningning Zhang, D. Fuhrmann, Stefan Merker, Harald Krautscheid
Abstract
[La(ONDI)]Cl, a hydroxamate MOF, exhibits high framework stability in aqueous solution and in common solvents. By modifying the reducing environment of synthesis, the amount of NDI˙ − radicals has been increased leading to higher electrical conductivity.
Topics & Concepts
Unpaired electronLanthanumReagentMetalChelationLigand (biochemistry)Metal-organic frameworkAqueous solutionRedoxChemistryInorganic chemistryConductivityRadicalPolymer chemistryMaterials scienceOrganic chemistryPhysical chemistryAdsorptionReceptorBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCorrosion Behavior and Inhibition