<i>J</i>-Driven dynamic nuclear polarization for sensitizing high field solution state NMR
Maria Grazia Concilio, Ilya Kuprov, Lucio Frydman
Abstract
states. Microwave irradiation can then generate a transient nuclear polarization build-up with high efficiency, at all magnetic fields that are relevant in contemporary NMR, and for all rotational diffusion correlation times that occur in small- and medium-sized molecules in conventional solvents.
Topics & Concepts
CIDNPHyperfine structurePolarization (electrochemistry)Larmor precessionNuclear magnetic resonance spectroscopyRelaxation (psychology)ChemistrySolid-state nuclear magnetic resonanceSinglet stateTwo-dimensional nuclear magnetic resonance spectroscopyNuclear magnetic resonanceNMR spectra databaseMagnetic fieldChemical physicsMolecular physicsSpectral lineAtomic physicsPhysicsPhysical chemistryQuantum mechanicsPsychologyExcited stateSocial psychologyAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyAtomic and Subatomic Physics Research