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Photocatalytic Degradation of Wastewater by Molecularly Imprinted Ag2S-TiO2 with High-selectively

Xian Liu, Lei Zhu, Xun Wang, Xide Meng

2020Scientific Reports41 citationsDOIOpen Access PDF

Abstract

Abstract The molecular imprinting technique is a new method for preparing molecularly imprinted polymers (MIPs) with specific molecular recognition sites for individual target molecules. In this study, Ag 2 S-MIP-TiO 2 nanocomposite was synthesized by a sol-gel-deposition method with ethyl p-hydroxybenzoate as an imprinting molecule. The obtained powder was characterized by XRD and other analytical methods. The results show that the obtained Ag 2 S-MIP-TiO 2 nanocomposite demonstrates better catalytic performance than pure anatase TiO 2 . The degradation efficiency of ethyl p-hydroxybenzoate during 1.5 h of the photocatalytic reaction is 92.22%, which is 42% higher than pure TiO 2 . The selectivity factor for the treatment of ethyl p-hydroxybenzoate compared to phenol using Ag 2 S-MIP-TiO 2 reached 3.571, which is 72% higher than pure TiO 2 .

Topics & Concepts

Molecular imprintingAnataseMolecularly imprinted polymerPhotocatalysisNanocompositePhenolPolymerDegradation (telecommunications)SelectivityMoleculeChemical engineeringNuclear chemistryMaterials scienceHydroxybenzoateAnilineCatalysisChemistryNanotechnologyOrganic chemistryComputer scienceTelecommunicationsEngineeringAdvanced Photocatalysis TechniquesAnalytical chemistry methods developmentCatalytic Processes in Materials Science
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