Effect of Fusion Manner of Concave Molecules on the Properties of Resulting Nanoboats
Yujun Song, Gang Zhang
Abstract
A boat-shaped compound, which can be viewed as the fusion of two concave molecules with crossed quinacridone and indolocarbazole throughout, was synthesized and characterized. The investigation determined that the fusion manner of two concave molecules has little influence on the molecular curvature and aromaticity when compared with its congener containing crossed indolocarbazole throughout. The situation of carbonyl groups is critical in adjusting the electronic structure and physicochemical properties due to the fixed position of nitrogen atoms.
Topics & Concepts
ChemistryMoleculeFusionAromaticityCurvatureCrystallographyCongenerStereochemistryOrganic chemistryGeometryLinguisticsMathematicsPhilosophySynthesis and Properties of Aromatic CompoundsFullerene Chemistry and ApplicationsLuminescence and Fluorescent Materials