<i>N</i>-Methylation of Amines with Methanol Catalyzed by Iridium(I) Complexes Bearing an N,O-Functionalized NHC Ligand
Miguel González-Lainez, M. Victoria Jiménez, Ramón Azpíroz, Vincenzo Passarelli, F. Javier Modrego, Jesús J. Pérez‐Torrente
Abstract
1H and 13C NMR spectra of the organometallic compounds and N-methylated amines, catalyst screening and optimization, isotopic labeling experiments, and DFT-optimized structures (PDF). \nCoordinates (XYZ).
Topics & Concepts
ChemistryCatalysisDeprotonationMedicinal chemistryIridiumDenticityLigand (biochemistry)Cationic polymerizationPyridineMethanolAnilineStereochemistryOrganic chemistryMetalIonReceptorBiochemistryAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysisCatalytic Cross-Coupling Reactions