Multifunctional Catalysis by a One-Dimensional Copper(II) Metal Organic Framework Containing Pre-existing Coordinatively Unsaturated Sites: Intermolecular C–N, C–O, and C–S Cross-Coupling; Stereoselective Intramolecular C–N Coupling; and Aziridination Reactions
Sagarmani Rasaily, Debesh Sharma, Sajan Pradhan, Nilankar Diyali, Shivanand Chettri, Bikram Gurung, Sudarsan Tamang, Anand Pariyar
Abstract
was applied as the catalyst for the synthesis of a library of aziridines that gives yields of up to 99% with more than 93% recyclability for each cycle.
Topics & Concepts
ChemistryIntramolecular forceIntermolecular forceStereoselectivityCopperCoupling (piping)CatalysisMetalComputational chemistryStereochemistryPolymer chemistryMoleculeOrganic chemistryMechanical engineeringEngineeringSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsMetal-Organic Frameworks: Synthesis and Applications