Photo- and triboluminescent robust 1D polymers made of Mn(<scp>ii</scp>) halides and <i>meta</i>-carborane based bis(phosphine oxide)
Alexander V. Artem’ev, Maria P. Davydova, Alexey S. Berezin, Taisiya S. Sukhikh, Denis G. Samsonenko⧫
Abstract
The 1D CPs of [Mn(L)X<sub>2</sub>]<sub>n</sub> type (X = Cl, Br, I), designed on 1,7-bis(diphenylphosphinyl)-<italic>m</italic>-carborane (L), show bright phosphorescence and triboluminescence, as well as exhibit thermo- and solvatochromic luminescence.
Topics & Concepts
CarboraneHalidePhosphorescencePhosphineSolvatochromismLuminescenceTriphenylphosphine oxidePhosphine oxideMaterials scienceOxidePolymerPolymer chemistryChemistryCrystallographyTriphenylphosphineMedicinal chemistryInorganic chemistryPhysicsOrganic chemistryMoleculeFluorescenceOptoelectronicsOpticsCatalysisLuminescence and Fluorescent MaterialsLanthanide and Transition Metal ComplexesOrganic Light-Emitting Diodes Research