Microstructure and properties of nano-laminated Y3Si2C2 ceramics fabricated via in situ reaction by spark plasma sintering
Linkun Shi, Xiaobing Zhou, Jian‐Qing Dai, Ke Chen, Qing Huang, Qing Huang
Abstract
Abstract A nano-laminated Y 3 Si 2 C 2 ceramic material was successfully synthesized via an in situ reaction between YH 2 and SiC using spark plasma sintering technology. A MAX phase-like ternary layered structure of Y 3 Si 2 C 2 was observed at the atomic-scale by high resolution transmission electron microscopy. The lattice parameters calculated from both X-ray diffraction and selected area electron diffraction patterns are in good agreement with the reported theoretical results. The nano-laminated fracture of kink boundaries, delamination, and slipping were observed at the tip of the Vickers indents. The elastic modulus and Vickers hardness of Y 3 Si 2 C 2 ceramics (with 5.5 wt% Y 2 O 3 ) sintered at 1500 °C were 156 and 6.4 GPa, respectively. The corresponding values of thermal and electrical conductivity were 13.7 W·m -1 ·K -1 and 6.3×10 5 S·m -1 , respectively.