The elusive dynamics of aqueous permanganate photochemistry
Omer S. Haggag, Partha Malakar, Pavel Pokhilko, John F. Stanton, Anna I. Krylov, Sanford Ruhman
Abstract
) fragments, is discussed. Finally, periodic modulations detected in the pump-probe signal are assigned to ground-state vibrational coherences excited by impulsive Raman. Their wavelength-dependent absolute phases outline the borders between adjacent electronic transitions in the linear spectrum of permanganate.
Topics & Concepts
PermanganateAqueous solutionDecompositionChemistryPhotochemistryDynamics (music)Organic chemistryPhysicsAcousticsAdvanced Chemical Sensor TechnologiesAnalytical Chemistry and SensorsRadical Photochemical Reactions