Tailoring stability, catalytic activity and selectivity of covalent metal–organic frameworks <i>via</i> steric modification of metal nodes
Haiyan Duan, Xu Chen, Yinan Yang, Jianping Zhao, Xiao‐Chun Lin, Wen-Jing Tang, Qiang Gao, Guo‐Hong Ning, Dan Li
Abstract
A novel and efficient strategy was developed to enhance the stability, control the catalytic activity, and improve the selectivity of Cu( i ) cyclic trinuclear unit (Cu-CTU)-based metal–organic frameworks by steric modification of copper nodes.
Topics & Concepts
Steric effectsSelectivityCatalysisCopperCovalent bondMetalMetal-organic frameworkChemistryCombinatorial chemistryOrganic chemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsNanomaterials for catalytic reactions