Photoinduced transition-metal- and external-photosensitizer-free intramolecular aryl rearrangement <i>via</i> C(Ar)–O bond cleavage
Qian Dou, Chao‐Jun Li, Huiying Zeng
Abstract
“We report a protocol for photoinduced transition-metal- and external-photocatalyst-free intramolecular heteroaryl/aryl rearrangement reactions of 2-heteroaryl/aryloxybenzaldehydes. The protocol was compatible with a variety of functionalities.
Topics & Concepts
Intramolecular forcePhotosensitizerArylChemistryBond cleavagePhotochemistryCleavage (geology)Transition metalMetalStereochemistryCatalysisMaterials scienceOrganic chemistryAlkylFracture (geology)Composite materialCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSynthesis of Indole Derivatives