Synthetic utility of functionalized alkylsilyl peroxides for Fe-catalyzed and visible-light-promoted radical transformation
Jiahao Liu, Shiyong Liu, Zhe Wang, Terumasa Kato, Yan Liu, Keiji Maruoka
Abstract
α-Keto-, β-acetoxy- and β-amidoalkylsilyl peroxides are prepared from various precursors and utilized for Fe-catalyzed and visible-light-promoted radical functionalization with coupling partners under mild conditions with a broad substrate scope.
Topics & Concepts
CatalysisVisible spectrumTransformation (genetics)ChemistryPhotochemistryPhotoredox catalysisCombinatorial chemistryPhotocatalysisOrganic chemistryMaterials scienceOptoelectronicsBiochemistryGeneRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods