<i>nor</i>-<i>seco</i>-Cucurbit[10]uril-based Supramolecular Assembly for Ultralong Afterglow Room-Temperature Phosphorescence Material and Metal Ion Detection
Ran Cen, Ming Liu, Chun Liu, Qin Hui Leng, Qian Ren, Zhu Tao, Xin Xiao
Abstract
A multifunctional supramolecular assembly, comprising nor - seco -cucurbit[10]uril ( ns -Q[10]) and tripyridine-bridged 4-(4-bromophenyl)pyridine (BTPY), has been constructed. The host–guest interaction between BTPY and ns -Q[10] resulted in a decrease in the singlet–triplet splitting energy (Δ E ST ), thereby enhancing the intersystem crossing process. Furthermore, the multiple hydrogen bonding interactions between BTPY@ ns -Q[10] assembly and poly(vinyl alcohol) (PVA), as well as its own host–guest interaction, inhibited the nonradiative transitions, resulting in long-lived room temperature phosphorescence (RTP) (τ = 261.3 ms). This RTP material provided a potential method for constructing RTP materials for information encryption and anticounterfeiting through a host–guest strategy. Moreover, the terpyridine component of BTPY, known for its strong metal coordination ability, enables the BTPY@ ns -Q[10] assembly to rapidly detect Fe 2+ and Fe 3+ ions in aqueous solution.