Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
Jean‐Pascal Sutter, Virginie Béreau, Valentin Jubault, Kateryna Bretosh, Céline Pichon, Carine Duhayon
Abstract
slow relaxation of their magnetization) in order to highlight the essential chemical and structural parameters for achieving strong axial anisotropy. The use of PBP complexes to impart controlled magnetic anisotropy in polynuclear species such as SMMs or SCMs is also addressed. This review of the magnetic anisotropies associated with a pentagonal bipyramidal coordination sphere for transition metal and lanthanide ions is intended to highlight some general trends that can guide chemists towards designing a compound with specific properties.
Topics & Concepts
Pentagonal bipyramidal molecular geometryLanthanideAnisotropyCoordination sphereCrystallographyMagnetic anisotropyCoordination geometryIonCoordination numberMaterials scienceMagnetizationChemistryTransition metalRelaxation (psychology)Metal ions in aqueous solutionMetalCondensed matter physicsGeometryCrystal structureMagnetic fieldMoleculePhysicsMetallurgyCatalysisMathematicsOpticsOrganic chemistryPsychologyHydrogen bondSocial psychologyQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications