Ru‐TsDPEN catalysts and derivatives in asymmetric transfer hydrogenation reactions
Ashish A. Mishra, Bhalchandra M. Bhanage
Abstract
This review summarizes current developments, novel synthetic routes for Ruthenium tethered chiral catalyst, and its derivatives along with its application in asymmetric synthesis. The review also covers derivatization in tethering unit, modification in N-monofunctionalized ligand as well as ligation of other ligand with Ru metal in chiral catalyst. Apparently, the effect of a modified tethered catalyst in the enantioselective synthesis of chiral products as well as in synthetic chemistry is also discussed in detail.
Topics & Concepts
ChemistryEnantioselective synthesisRutheniumCatalysisTransfer hydrogenationCombinatorial chemistryDerivatizationLigand (biochemistry)Chiral ligandMetalOrganic chemistryHigh-performance liquid chromatographyBiochemistryReceptorAsymmetric Hydrogenation and CatalysisCatalysis for Biomass ConversionSurface Chemistry and Catalysis