Ce(III)/Photoassisted Synthesis of Amides from Carboxylic Acids and Isocyanates
Hao‐Cong Li, Guannan Li, Kai Sun, Xiaolan Chen, Ming-Xuan Jiang, Lingbo Qu, Bing Yu
Abstract
The Ce(III)-photocatalyzed synthesis of amides from carboxylic acids and aryl isocyanates was developed. The reaction includes the formation of alkyl radicals from carboxylic acids followed by radical addition to the electron-deficient carbon of isocyanate.
Topics & Concepts
ChemistryIsocyanateArylRadicalAlkylOrganic chemistryCarboxylic acidPolymer chemistryPolyurethaneSulfur-Based Synthesis TechniquesChemical Synthesis and AnalysisChemical Synthesis and Reactions