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Anode Catalysts in CO<sub>2</sub> Electrolysis: Challenges and Untapped Opportunities

Ádám Vass, Attila Kormányos, Zsófia Kószó, Balázs Endrődi, Csaba Janáky

2022ACS Catalysis140 citationsDOIOpen Access PDF

Abstract

electrolyzer cells from the past 5 years, to shed light on the role of the anodic oxygen evolution catalyst. We analyze how different cell architectures provide different local chemical environments at the anode surface, which in turn determines the pool of applicable anode catalysts. We uncover the factors that led to either a strikingly high current density operation or an exceptionally long lifetime. On the basis of our analysis, we provide a set of criteria that have to be fulfilled by an anode catalyst to achieve high performance. Finally, we provide an outlook on using alternative anode reactions (alcohol oxidation is discussed as an example), resulting in high-value products and higher energy efficiency for the overall process.

Topics & Concepts

AnodeElectrolysisCatalysisElectrochemistryOxygen evolutionMaterials scienceChemical engineeringProcess engineeringNanotechnologyEnvironmental scienceChemistryElectrodeOrganic chemistryPhysical chemistryElectrolyteEngineeringCO2 Reduction Techniques and CatalystsElectrocatalysts for Energy ConversionAdvanced battery technologies research