Electrochemical deamination functionalization <i>via</i> C–N bond cleavage and radical formation
Zhenlei Zou, Jie Dong, Yi Shi, Wangzhe Chen, Weigang Zhang, Yi Wang
Abstract
activation of C-N bonds, affording different functionalizations under mild reaction conditions with a shorter reaction time. In light of the ever-increasing importance of electrosynthesis spanning most disciplines of the chemical sciences, we review recent developments in electrochemically promoted radical deamination functionalization over the past decade (from 2015 to 2025). Special emphasis is put on various electrochemical transformation paths and proposed mechanisms.
Topics & Concepts
ElectrosynthesisSurface modificationChemistryDeaminationElectrochemistryCleavage (geology)Bond cleavageCombinatorial chemistryCatalysisOrganic chemistryOrganic synthesisChemical modificationPhotochemistryReaction mechanismRadical ionPhotoredox catalysisOxidative deaminationPolymer chemistryReaction conditionsElectrocatalystElectrochemical Analysis and Applications