Photocatalytic decarboxylative phosphorylation of <i>N</i>-aryl glycines
Jiangwei Wen, Xue Sun, Kelu Yan, Tingtao Yan, Zhen Liu, Yang Li, Jianjing Yang
Abstract
A straightforward and practical strategy for decarboxylphosphatization of N -aryl glycines to access α-amino phosphine oxides, enabled by visible-light photoredox catalysis in the absence of metal, and base, has been described.
Topics & Concepts
ChemistryArylPhotocatalysisPhosphineCatalysisVisible spectrumBase (topology)PhotochemistryCombinatorial chemistryOrganic chemistryAlkylOptoelectronicsMathematical analysisMathematicsPhysicsRadical Photochemical ReactionsChemical Synthesis and AnalysisSulfur-Based Synthesis Techniques