Stereoselective construction of azepine-containing bridged scaffolds via organocata-lytic bicyclization of yne-allenone esters with nitrones
Mengfan Li, Shaoqing Shi, Ting Xu, Qian Zhang, Wen‐Juan Hao, Shuliang Wang, Jianyi Wang, Shu‐Jiang Tu, Bo Jiang
Topics & Concepts
RegioselectivityStereocenterChemistryAnnulationStereoselectivityAzepineConjugated systemDensity functional theoryDiradicalStereochemistryUmpolungCombinatorial chemistryCatalysisComputational chemistryOrganic chemistryPolymerNucleophilePhysicsNuclear physicsEnantioselective synthesisExcited stateSinglet stateAsymmetric Synthesis and CatalysisChemical synthesis and alkaloidsCatalytic C–H Functionalization Methods