Electrocatalytic reduction of CO<sub>2</sub> to CO by a series of organometallic Re(<scp>i</scp>)-tpy complexes
Shriya Saha, Thomas Doughty, Dibyendu Banerjee, Sunil Kumar Patel, Dibyendu Mallick, E. Siva Subramaniam Iyer, Souvik Roy, Raja Mitra
Abstract
of the proton sources. The TDDFT and ultrafast transient absorption spectroscopy (TAS) studies showed combined charge transfer bands of ILCT and MLCT. Amongst the series, the Re-complex containing a ferrocenyl-substituted terpyridine ligand (Re5) shows an additional intra-ligand charge transfer band and was probed using UV-Vis spectroelectrochemistry.
Topics & Concepts
Series (stratigraphy)Reduction (mathematics)ChemistryGroup 2 organometallic chemistryOrganometallic chemistryCatalysisStereochemistryCombinatorial chemistryOrganic chemistryMathematicsMoleculeBiologyGeometryPaleontologyCO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisIonic liquids properties and applications