Litcius/Paper detail

High Thermal Stability of κ-Ga2O3 Grown by MOCVD

Jun‐Hee Lee, Honghyuk Kim, Lakshay Gautam, Manijeh Razeghi

2021Crystals27 citationsDOIOpen Access PDF

Abstract

We report a high thermal stability of kappa gallium oxide grown on c-plane sapphire substrate by metal organic chemical vapor deposition. Kappa gallium oxide is widely known as a metastable polymorph transitioning its phase when subjected to a high temperature. Here, we show the kappa gallium oxide whose phase is stable in a high temperature annealing process at 1000 °C. These oxide films were grown at 690 °C under nitrogen carrier gas. The materials showed high electrical resistivity when doped with silicon, whereas the film conductivity was significantly improved when doped with both indium and silicon. This work provides a pathway to overcoming limitations for the advance in utilizing kappa gallium oxide possessing superior electrical characteristics.

Topics & Concepts

GalliumMetalorganic vapour phase epitaxyMaterials scienceIndiumChemical vapor depositionOxideElectrical resistivity and conductivityAnnealing (glass)WaferSiliconDopingSapphireAnalytical Chemistry (journal)Chemical engineeringEpitaxyNanotechnologyOptoelectronicsChemistryMetallurgyOpticsLayer (electronics)LaserChromatographyElectrical engineeringPhysicsEngineeringGa2O3 and related materialsZnO doping and propertiesElectronic and Structural Properties of Oxides