A “competitive occupancy” strategy toward Co–N<sub>4</sub> single-atom catalysts embedded in 2D TiN/rGO sheets for highly efficient and stable aromatic nitroreduction
Ying Gu, Aiping Wu, Lei Wang, Dongxu Wang, Haijing Yan, Peng Yu, Ying Xie, Chungui Tian, Fanfei Sun, Honggang Fu
Abstract
Single-atom M–N-based catalysts have been synthesized based on the “competitive occupancy” of Ti species and Co<sup>2+</sup> (Ni<sup>2+</sup><italic>etc.</italic>) on GO, and can be used as a highly active and stable hydrogenation catalyst.
Topics & Concepts
CatalysisTinAtom (system on chip)ChemistryMaterials scienceCrystallographyInorganic chemistryOrganic chemistryComputer scienceEmbedded systemNanomaterials for catalytic reactionsAdvanced Photocatalysis TechniquesAmmonia Synthesis and Nitrogen Reduction