Oxidation reactions of a versatile, two-coordinate, acyclic iminosiloxysilylene
Dominik Reiter, Philipp Frisch, Daniel Wendel, Fabian M. Hörmann, Shigeyoshi Inoue
Abstract
could be achieved, but also the conversion into a reactive donor-free silaimine, which itself turned out to be a useful reagent for small molecule activation. In addition, 1 served as an excellent precursor for gaining access to donor-stabilized heavier carbonyl compounds. Our results thus provide further insights into the chemistry of low-valent silicon at the interface between carbon and transition metals.
Topics & Concepts
Reactivity (psychology)ChemistrySiliconCongenerCarbon fibersCombinatorial chemistryTransition metalClass (philosophy)Computational chemistryOrganic chemistryMaterials scienceComputer scienceCatalysisComposite numberComposite materialMedicineArtificial intelligenceAlternative medicinePathologySynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryOrganometallic Complex Synthesis and Catalysis