Homoleptic Ni(<scp>ii</scp>) dithiocarbamate complexes as pre-catalysts for the electrocatalytic oxygen evolution reaction
Sarvesh Kumar Pal, Baghendra Singh, Jitendra Kumar Yadav, Chote Lal Yadav, Michael G. B. Drew, Nanhai Singh, Arindam Indra, Kamlesh Kumar
Abstract
Functionalized Ni( ii ) dithiocarbamate complexes act as pre-catalysts for electrocatalytic oxygen evolution reaction (OER) in 1.0 M KOH and active catalyst, Ni(O)OH produces a current density of 10 mA cm −2 at an overpotential of 330 mV.
Topics & Concepts
HomolepticCatalysisDithiocarbamateChemistryOxygen evolutionOxygenCombinatorial chemistryInorganic chemistryElectrochemistryOrganic chemistryMetalPhysical chemistryElectrodeElectrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsFuel Cells and Related Materials