Hydrogen-bonded organic frameworks of twisted polycyclic aromatic hydrocarbon
Yuto Suzuki, Norimitsu Tohnai, Akinori Saeki, Ichiro Hisaki
Abstract
A dibenzo[g,p]chrysene (DBC)-based hydrogen-bonded organic framework (HOF) was constructed by shape-fitted docking of the twisted π-conjugated core. The activated HOF, possessing exactly eclipsed stacking of the DBC cores, (CPDBC-1a) had a BET surface area of 1548 m2 g-1 and possessed photoconductivity.
Topics & Concepts
ChryseneHydrocarbonPolycyclic aromatic hydrocarbonHydrogenAromatic hydrocarbonChemistryAnthraceneMaterials sciencePhotochemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsLuminescence and Fluorescent Materials