Highly efficient Markovnikov hydroaminocarbonylation of alkenes and alkynes catalyzed by a “soluble” heterogeneous Pd catalyst
Xin Zhou, Zhaozhan Wang, Bo Yu, Shaoping Kuang, Wei Sun, Yong Yang
Abstract
Ultrafine Pd NPs dispersed in phosphine-built-in porous organic cage exhibited superior activity and Markovnikov regioselectivity for hydroaminocarbonylation of alkenes and alkynes to access a wide arrange of branched amides with strong stability.
Topics & Concepts
Markovnikov's ruleCatalysisRegioselectivityChemistryPhosphineOrganic chemistryCombinatorial chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsOrganoboron and organosilicon chemistry