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Identification and manipulation of dynamic active site deficiency-induced competing reactions in electrocatalytic oxidation processes

Runjia Lin, Liqun Kang, Tianqi Zhao, Jianrui Feng, Verónica Celorrio, Guohui Zhang, Giannantonio Cibin, Anthony Kucernak, Dan J. L. Brett, Furio Corà, Ivan P. Parkin, Guanjie He

2022Energy & Environmental Science204 citationsDOIOpen Access PDF

Abstract

A detrimental competition between the urea oxidation reaction (UOR) and oxygen evolution reaction is identified. Strategies are proposed to alleviate such competition and boost the performance of the UOR and other organic compound oxidation reactions.

Topics & Concepts

RedoxCompetition (biology)Identification (biology)ChemistryOxygen evolutionUreaCombinatorial chemistryBiochemistryInorganic chemistryElectrochemistryBiologyElectrodeEcologyPhysical chemistryElectrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsFuel Cells and Related Materials
Identification and manipulation of dynamic active site deficiency-induced competing reactions in electrocatalytic oxidation processes | Litcius