A new metal–organic framework based on rare [Zn<sub>4</sub>F<sub>4</sub>] cores for efficient separation of C<sub>2</sub>H<sub>2</sub>
Wen‐Juan Shi, Yong‐Zhi Li, Jing Chen, Run-Han Su, Lei Hou, Yao-Yu Wang, Zhonghua Zhu
Abstract
Assembly via 1,4-benzenedicarboxylate linker and Zn 2+ ions afforded a new MOF containing novel [Zn 4 F 4 ] cubane cores, showing excellent C 2 H 2 separation from C 2 H 2 –CO 2 and C 2 H 2 –CH 4 mixtures.
Topics & Concepts
CubaneMetalMonte Carlo methodMetal-organic frameworkMaterials scienceChemistryCrystallographyPhysical chemistryCrystal structureOrganic chemistryMathematicsAdsorptionStatisticsMetal-Organic Frameworks: Synthesis and ApplicationsSulfur Compounds in BiologyInorganic Fluorides and Related Compounds