Photocatalyst-free hydroacylations of electron-poor alkenes and enones under visible-light irradiation
Ádám Márk Pálvölgyi, Florian Ehrschwendtner, Michael Schnürch, Katharina Bica
Abstract
-quinone methide substrates could be used. The protocol enabled further derivatizations and it could also be extended to a few unactivated alkenes. Moreover, the nature of the radical process was also investigated.
Topics & Concepts
PhotocatalysisIrradiationPhotochemistryElectronVisible spectrumChemistryMaterials scienceOptoelectronicsPhysicsOrganic chemistryNuclear physicsCatalysisRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesOxidative Organic Chemistry Reactions