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A quinary WTaCrVHf nanocrystalline refractory high-entropy alloy withholding extreme irradiation environments

Osman El‐Atwani, H.T. Vo, Matheus A. Tunes, C. Lee, Andrew Alvarado, N. Krienke, Jonathan D. Poplawsky, Aaron A. Kohnert, Jonathan Gigax, W.-Y. Chen, M. Li, Yongqiang Wang, Jan Wróbel, D. Nguyen-Manh, Jon K. Baldwin, O. U. Tukac, Eda Aydogan, Saryu Fensin, Enrique Martínez

2023Nature Communications149 citationsDOIOpen Access PDF

Abstract

In the quest of new materials that can withstand severe irradiation and mechanical extremes for advanced applications (e.g. fission & fusion reactors, space applications, etc.), design, prediction and control of advanced materials beyond current material designs become paramount. Here, through a combined experimental and simulation methodology, we design a nanocrystalline refractory high entropy alloy (RHEA) system. Compositions assessed under extreme environments and in situ electron-microscopy reveal both high thermal stability and radiation resistance. We observe grain refinement under heavy ion irradiation and resistance to dual-beam irradiation and helium implantation in the form of low defect generation and evolution, as well as no detectable grain growth. The experimental and modeling results-showing a good agreement-can be applied to design and rapidly assess other alloys subjected to extreme environmental conditions.

Topics & Concepts

QuinaryHigh entropy alloysMaterials scienceIrradiationNanocrystalline materialAlloyGrain boundaryNuclear engineeringNanotechnologyMicrostructureMetallurgyNuclear physicsPhysicsEngineeringHigh Entropy Alloys StudiesHigh-Temperature Coating BehaviorsAdvanced Materials Characterization Techniques
A quinary WTaCrVHf nanocrystalline refractory high-entropy alloy withholding extreme irradiation environments | Litcius