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Palladium-catalyzed C–H trifluoromethylselenolation of arenes with [Me<sub>4</sub>N][SeCF<sub>3</sub>] and an oxidant

Lei Liu, Yu‐Cheng Gu, Cheng‐Pan Zhang

2022Chemical Communications16 citationsDOI

Abstract

The first directing-group-assisted C(sp 2 )–H trifluoromethylselenolation of arenes with the nucleophilic [Me 4 N][SeCF 3 ] reagent in the presence of a Pd-catalyst and oxidant is described.

Topics & Concepts

PalladiumCatalysisChemistryCombinatorial chemistryMedicinal chemistryOrganic chemistryFluorine in Organic ChemistryCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques
Palladium-catalyzed C–H trifluoromethylselenolation of arenes with [Me<sub>4</sub>N][SeCF<sub>3</sub>] and an oxidant | Litcius