Hydrogen Peroxide Detection Using Prussian Blue‐modified 3D Pyrolytic Carbon Microelectrodes
Sheida Esmail Tehrani, Long Quang Nguyen, Giulia Garelli, Bettina M. Jensen, Tautgirdas Ruzgas, Jenny Emnéus, Stephan Sylvest Keller
Abstract
Abstract A highly sensitive amperometric Prussian blue‐based hydrogen peroxide sensor was developed using 3D pyrolytic carbon microelectrodes. A 3D printed multielectrode electrochemical cell enabled simultaneous highly reproducible Prussian blue modification on multiple carbon electrodes. The effect of oxygen plasma pre‐treatment and deposition time on Prussian blue electrodeposition was studied. The amperometric response of 2D and 3D sensors to the addition of hydrogen peroxide in μM and sub‐μM concentrations in phosphate buffer was investigated. A high sensitivity comparable to flow injection systems and a detection limit of 0.16 μM was demonstrated with 3D pyrolytic carbon microelectrodes at stirred batch condition