Water as a solvent: transition metal catalyzed dehydrogenation of alcohols going green
Ishani Borthakur, Saloni Kumari, Sabuj Kundu
Abstract
. Among these alternatives, water is unquestionably an ideal solvent as it is abundant, cheap, non-toxic, and non-flammable. In the last few decades, a breakthrough has been achieved in the field of transition metal-catalyzed dehydrogenation of alcohols and the related chemistry for the sustainable synthesis of a wide range of valuable compounds. Although a large number of reports with new potential are published every year following this alcohol dehydrogenation strategy, the utilization of water as a solvent in alcohol dehydrogenation and related coupling reactions is yet to be highlighted properly. This review summarizes the advances in metal-catalyzed dehydrogenative functionalization of alcohols using water as a solvent.