Synergetic magnetic and luminescence switching <i>via</i> solid state phase transitions of the dysprosium–dianthracene complex
Jing‐Cui Liu, Xin‐Da Huang, Qian Zou, Song‐Song Bao, Xizhang Wang, Jingyuan Ma, Li‐Min Zheng
Abstract
A dinuclear complex Dy<sub>2</sub>L<sub>2</sub>(<bold>depma2</bold>)Cl<sub>2</sub> containing a pre-photodimerized dianthracene phosphonate ligand (<bold>depma2</bold>) undergoes consecutive two-step structural transformation upon heating <bold>depma2</bold>, accompanied by a synergetic switching of the photoluminescence and magnetic dynamics.
Topics & Concepts
DysprosiumPhotoluminescenceMaterials scienceLuminescencePhosphonatePhase (matter)CrystallographySolid-statePhase transitionCondensed matter physicsPhysical chemistryOptoelectronicsInorganic chemistryChemistryPhysicsOrganic chemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganometallic Complex Synthesis and Catalysis