Synthesis of Sulfinamidines and Sulfinimidate Esters by Transfer of Nitrogen to Sulfenamides
Michael Andresini, Mauro Spennacchio, Giuseppe Romanazzi, Fulvio Ciriaco, Guy J. Clarkson, Leonardo Degennaro, Renzo Luisi
Abstract
In this work we report a new synthetic tactic for the straightforward preparation of hardly accessible sulfinamidines and sulfinamide esters, by using a simple metal-free protocol. The process is robust and uses readily available sulfenamides as the S-donor and sulfonyloxycarbamates as the N-source. The scope and mechanism have also been investigated.
Topics & Concepts
ChemistryScope (computer science)Combinatorial chemistryNitrogenSimple (philosophy)Process (computing)Organic chemistryComputer scienceProgramming languagePhilosophyEpistemologySulfur-Based Synthesis TechniquesSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods