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Advances and challenges of metal organic frameworks (MOFs) and derivatives in photoelectrocatalytic water splitting

Xin-Jie Tian, Sijia Guo, Zhengyi Wu, Na Xu, Guan‐Qun Han, Yong‐Ming Chai, Bin Dong

2025Materials Horizons6 citationsDOI

Abstract

ligand bonds. They offer high specific surface areas, abundant metal active sites, large pore volumes, and customizable structures and compositions, making them highly favorable for applications in photoelectrocatalysis. This review discusses the advancements in photoelectrocatalytic hydrogen production technology using metal-organic frameworks (MOFs) and derivatives. It covers the principles of photoelectrocatalysis, preparation methods for MOF catalysts and strategies for performance enhancement. These strategies include improving light absorption, enhancing carrier separation efficiency, and ensuring stability. The paper also discusses the current challenges and future directions of photoelectrocatalytic water splitting technology. Overall, this review offers a thorough theoretical framework and practical insights for researchers in this field.

Topics & Concepts

Metal-organic frameworkNanotechnologyMaterials scienceWater splittingPhotocatalysisChemistryCatalysisOrganic chemistryAdsorptionAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in CatalysisMetal-Organic Frameworks: Synthesis and Applications
Advances and challenges of metal organic frameworks (MOFs) and derivatives in photoelectrocatalytic water splitting | Litcius