A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks
Lei Zhang, Rong‐Ran Liang, Hang Cheng, Hai‐Ying Wang, Lin Sun, Lei Xu, Dairong Liu, Zhenyi Zhang, Xingmin Zhang, Fei‐Fan Chang, Shengyu Zhao, Wei Huang
Abstract
A general solution-phase synthetic strategy is developed to construct both porous organic cages (POCs) and covalent organic frameworks (COFs) by simply stirring and heating organic solvent/water solutions of aldehydes and amines in the presence of MOH (M = Na, K, and Cs).
Topics & Concepts
Covalent bondPhenolPorosityPhase (matter)Organic solventSolventChemistryCovalent organic frameworkOrganic chemistryChemical engineeringEngineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials