Ligand-regulated photoinduced electron transfer within metal–organic frameworks for efficient photocatalysis
Yang Tang, Guanfeng Ji, Hanning Li, Hui Gao, Cheng He, Liang Zhao, Chunying Duan
Abstract
By judiciously controlling the twisted conjugation between ligands and coordinated carboxylates to inhibit intramolecular photoinduced electron transfer process, an acridone-based metal–organic framework was obtained for efficient photocatalysis.
Topics & Concepts
PhotocatalysisIntramolecular forcePhotoinduced electron transferElectron transferAcridonePhotochemistryMetalLigand (biochemistry)ChemistryMetal-organic frameworkMaterials scienceCatalysisStereochemistryOrganic chemistryReceptorAdsorptionBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis TechniquesPolyoxometalates: Synthesis and Applications