State-of-the-art of CO<sub>2</sub> capture with amino acid salt solutions
Rouzbeh Ramezani, Saeed Mazinani, Renzo Di Felice
Abstract
Abstract The emission of large amounts of CO 2 into the atmosphere is believed to be a major reason behind climate change, which has led to increased demand for CO 2 capture. Postcombustion CO 2 capture with chemical solvent is considered one of the most important technologies in order to reduce CO 2 emission. Amino acid salt solutions have attracted special attention in recent years due to their excellent physicochemical properties, e.g., low volatility, less toxicity, and high oxidative stability, as well as capture performance comparable with conventional amines. In this study, physicochemical properties of 20 amino acids are reported and their CO 2 absorption performance discussed. The topics covered in this review include the most relevant properties of amino acids including CO 2 loading capacity, cyclic capacity, equilibrium constant, density, viscosity, dissociation constant, CO 2 solubility, CO 2 diffusivity, reaction kinetic between CO 2 and amino acid salts, reaction rate constant, surface tension, heat of CO 2 absorption, precipitation, toxicity, solvent degradation, and corrosion rate. This review provides the most recent information available in the literature on the potential of using amino acid salts as a solvent for CO 2 capture which can help improve the performance of the CO 2 capture process from flue gas streams.