Catalytic mechanism and design principle of coordinately unsaturated single metal atom-doped covalent triazine frameworks with high activity and selectivity for CO<sub>2</sub>electroreduction
Lele Gong, Xiaowei Wang, Tao Zheng, Jerry Liu, Jie Wang, Yu‐Chia Yang, Jing Zhang, Xiao Han, Lipeng Zhang, Zhenhai Xia
Abstract
Electrochemical conversion of CO<sub>2</sub>to fuels needs highly active electrocatalysts. We establish the design principles to screen the best catalysts from the family of coordinately unsaturated/saturated transition metal covalent organic frameworks.
Topics & Concepts
TriazineCovalent bondCatalysisSelectivityElectrochemistryTransition metalDopingAtom (system on chip)MetalMaterials scienceCombinatorial chemistryChemistryNanotechnologyInorganic chemistryOrganic chemistryPolymer chemistryPhysical chemistryComputer scienceElectrodeOptoelectronicsEmbedded systemCO2 Reduction Techniques and CatalystsCovalent Organic Framework ApplicationsAdvanced Photocatalysis Techniques