Exploiting Hansen solubility parameters to tune porosity and function in conjugated microporous polymers
Jie Chen, Ting Qiu, Wei Yan, Charl F. J. Faul
Abstract
We expand our recently reported Bristol–Xi'an Jiaotong (BXJ) approach using simple salts to fine tune the porosity of conjugated microporous materials, from Buchwald–Hartwig to Sonogashira–Hagihara, oxidative and Suzuki cross-coupling reactions.
Topics & Concepts
Conjugated microporous polymerMicroporous materialPorositySonogashira couplingMaterials sciencePolymerConjugated systemSolubilityChemical engineeringPolymer chemistryOrganic chemistryChemistryComposite materialPalladiumCatalysisEngineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas Transport