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Low-Temperature Solution-Based Molybdenum Oxide Memristors

Raquel Azevedo Martins, Emanuel Carlos, Asal Kiazadeh, Rodrigo Martins, Jonas Deuermeier

2024ACS Applied Engineering Materials16 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide Solution-based memristors have gained significant attention in recent years due to their potential for the low-cost, scalable, and environmentally friendly fabrication of resistive switching devices. This study is focused on the fabrication and characterization of solution-based molybdenum trioxide (MoO 3 ) memristors under different annealing temperatures (200 to 400 °C). A MoO 3 ink recipe is developed using water as the main solvent, enabling a simplified and cost-effective fabrication process. Material analysis reveals the presence of a Mo 6+ oxidation state and an amorphous structure in the films annealed up to 250 °C. Electrical tests confirm a bipolar resistive switching behavior in the memristors according to the valence change mechanism (VCM). Endurance tests demonstrate stable memristors, indicating their robust nature after multiple cycles. Memristors annealed at 250 °C exhibit a nonvolatile behavior with a retention time up to 10 5 s under ambient air conditions. The high reproducibility observed in these memristors highlights their potential for practical applications and scalability.

Topics & Concepts

MemristorFabricationMaterials scienceResistive random-access memoryAnnealing (glass)Amorphous solidElectroformingNanotechnologyMolybdenumScalabilityResistive touchscreenNon-volatile memoryOptoelectronicsElectronic engineeringElectrodeComputer scienceComposite materialMetallurgyChemistryDatabaseComputer visionEngineeringMedicinePathologyLayer (electronics)Physical chemistryAlternative medicineOrganic chemistryAdvanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsFerroelectric and Negative Capacitance Devices