Computational study of the copolymerization mechanism of ethylene with methyl 2-acetamidoacrylate catalyzed by phosphine-sulfonate palladium complexes
Andleeb Mehmood, Xiaowei Xu, Waseem Raza, Deepak Kukkar, Ki‐Hyun Kim, Yi Luo
Abstract
In this research, a computational study is carried out to describe the insertion of a vital monomer, methyl 2-acetamidoacrylate (MAAA), into catalyst A (A = [(PO OMe,OMe )PdMe]) (PO OMe,OMe = 2[2-MeOC 6 H 4 ](2-SO 3 -5-MeC 6 H 4 )P).
Topics & Concepts
ChemistryPalladiumPhosphineCatalysisSulfonateEthyleneMonomerMechanism (biology)CopolymerPolymer chemistryMedicinal chemistryOrganic chemistryPolymerSodiumEpistemologyPhilosophyOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysis