High-Performance WSe<sub>2</sub> Top-Gate Devices with Strong Spacer Doping
Po‐Hsun Ho, Yuying Yang, Sui-An Chou, Ren‐Hao Cheng, Po-Heng Pao, Chao-Ching Cheng, Iuliana Radu, Chao-Hsin Chien
Abstract
Because of the lack of contact and spacer doping techniques for two-dimensional (2D) transistors, most high-performance 2D devices have been produced with nontypical structures that contain electrical gating in the contact regions. In the present study, we used chloroauric acid (HAuCl 4 ) as a strong p -dopant for WSe 2 monolayers used in transistors. The HAuCl 4 -doped devices exhibited a record-low contact resistance of 0.7 kΩ·μm under a doping concentration of 1.76 × 10 13 cm –2 . In addition, an extrinsic carrier diffusion phenomenon was discovered in the HAuCl 4 –WSe 2 system. With a suitably designed spacer length for doping, a normally off, high-performance underlap top-gate device can be produced without the application of additional gating in the contact and spacer regions.