Cyclohexene epoxidation with H<sub>2</sub>O<sub>2</sub> in the vapor and liquid phases over a vanadium-based metal–organic framework
Tae-Ung Yoon, Sol Ahn, Ah Reum Kim, Justin M. Notestein, Omar K. Farha, Youn‐Sang Bae
Abstract
A V-containing metal–organic framework exhibits significantly different catalytic mechanisms between liquid-phase and gas-phase cyclohexene oxidations.
Topics & Concepts
CyclohexeneVanadiumCatalysisLiquid phaseMetalPhase (matter)Inorganic chemistryMetal-organic frameworkGas phaseChemistryMaterials scienceOrganic chemistryAdsorptionThermodynamicsPhysicsMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications