Molecular modulation of nickel–salophen organic frameworks enables the selective photoreduction of CO<sub>2</sub>at varying concentrations
Xiaohan Yu, Mingzi Sun, Tianran Yan, Lin Jia, Mingyu Chu, Liang Zhang, Wei Huang, Bolong Huang, Yanguang Li
Abstract
Metal–salophen organic frameworks with dispersed metal centers and precise coordination environments were synthesized. The optimal sample exhibited great photocatalytic activity and near-unity CO selectivity over a wide range of CO 2 concentrations.
Topics & Concepts
NickelModulation (music)Metal-organic frameworkChemistryChemical engineeringMaterials sciencePhotochemistryInorganic chemistryOrganic chemistryAdsorptionPhysicsAcousticsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsAdvanced Photocatalysis Techniques